catena-Poly[[aqua­glycolatocopper(II)]-μ-chlorido]

نویسندگان

  • Hoong-Kun Fun
  • Jain John
  • Samuel Robinson Jebas
  • T Balasubramanian
چکیده

In the crystal structure of the title compound, [Cu(C(2)H(3)O(3))Cl(H(2)O)](n), the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. Two O atoms from a chelating glycolate anion, an O atom from a coordinated water mol-ecule and a chloride anion comprise the basal plane. A chloride ion from a neighbouring unit occupies the apical position and these Cu-Cl-Cu bridges link the aqua-glycolatocopper(II) units into one-dimensional chains along the [001] direction. These chains are connected by O-H⋯O and O-H⋯Cl hydrogen bonds, forming an infinite three-dimensional polymeric network.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008